Re: Not on Shuttle-
It was one of the extra safety measures they brought in following the Challenger disaster IIRC. It was doubtful that it would do any good, but the idea was not to smash the 'nauts against the side of the airlock as the wind caught them on the way out.
As the solid boosters and external fuel tanks could all be jettisoned I think the idea was that the shuttle was the emergency escape capsule. That didn't work out too well though.