@Pirate Dave
Radioactive waste /might/ cause a few interesting mutations. Maybe. Depending on the waste.
CO2 /might/ be beneficial to some plants. Maybe. If it's in low enough quantities.
If a /lot/ of the really bad radioactive waste (from a disposal site)was put in one place and leaked, it would cause a large amount of devastation in a /very/ confined area. We are talking a few dozen, or maybe a couple hundred meters here. So your disposal site leaks, and you kill everything for a hundred meters.
If your giant underground storage tank of CO2 suddenly escapes, you can kill every living thing for dozens of kilometres. Not just people, but plants too. Those plants, at night, require oxygen to survive. Admittedly, it takes a stupid amount of CO2 to kill a plant, but you most certainly can kill a plant with CO2. Non plants are basically boned.
Radioactive material isn’t good for any living being, but can be used in a productive fashion by humanity.
I think it is very fair to say that the leak OF A STORAGE FACILITY is equally bad. Remember what we’re talking about here. Storage facilities. We are not talking Chernobyl, or an atomic weapon where several pounds of highly radioactive and a few tonnes of marginally radioactive material are blow up and spread across a wide area, giving everything for hundreds of kilometres new and exotic cancers.
We’re talking about a gigantic cement hole in the ground that is monitored religiously developing a crack. Even if you just dumped all this stuff in a cave, provided you were remotely intelligent and designed your storage facility to not be capable of leaking wasted into the watershed, you’re golden for millennia.
Let me tell you how to store radioactive waste so you don’t actually have to /care/ about leaks:
Drill a very large hole as far down into the bedrock as you can. Fill with waste. Cover with cement. This is significantly below any part of the water table, and won’t be spreading or what have you. The cement plug might crack or erode, but there should be the better part of a kilometre worth of Other Stuff between your very small hole of radioactive wastes and the water table. Radioactive waste doesn’t “leak out.” It doesn’t ooze, drip or mix with the atmosphere. It’s METAL. It sits there and emits whatever form radiation that particular substance emits and otherwise doesn’t move.
CO2 is a gas: to store it in a carbon capture scenario, you are storing it at several times atmospheric pressure. One tiny crack in that storage container, (be it geological or otherwise,) and the pressure differential will evacuate all your stored CO2 very quickly. It will then spread: a cloud of suffocating death that will wipe out anything that requires oxygen for X distance around, where X is the result of a formula taking into account the amount of pressure the original deposit was under, the size of the hole (and how much the evacuating gasses erode the hole as they escape,) the topology of the area and the amount of CO2 stored at that location.
If you want to know how deadly CO2 can be to large areas, please ring up the United States Geological Survey (USGS) and arrange to spend some time talking with a volcanologist. They will set you straight.
A big lump of radioactive material, even if it is sitting in a field somewhere is a slow-acting threat to which there is plenty of time to respond, it is /incredibly/ localised, and a fantastically easy problem to solve.
A gigatonne of CO2 under thirty atmospheres of pressure escaping through a hole the size of a fridge is the ecological equivalent of a multi-kilometer carpet bomb.