Impossible...
...to compare the 2. They are completely different.
I have to say that I liked the Bourne Identity. Mainly for the mini car chase (I like minis). But another thing is that it got me reading the books, and they are AWESOME! The film is nothing like, except for the vaguest outline of the story. But still a fairly good film.
Bond, on the other hand, is a parody. It is not meant to be realistic, it is taking the weewee out of itself. Yes, Bond is a misogynist. It's funny. Yes it's unrealistic, but it's funny. Bond is meant to be entertainment, not a documentary.
<TONGUE IN CHEEK RANT>You know, I wasn't quite sure about Matt Damon, but now I can clearly see him as the character portrayed in Team America. He is a whiny, self-obsessed idiot, and to criticise another, completely different film series like that is just stupid. He should just stick to shouting "Matt Damon, Matt Damon!", it would be more pleasant on our ears.</TONGUE IN CHEEK RANT>