When will 32nm matter?
Sun's current processors (US-IV+ and US-T1) are 90nm designs. SPARC64-VI (dual-core Olympus chip) is a 90nm design. Niagara2, Rock (2008), and Jupiter (SPARC64-VI+, also 2008) are 65nm designs. Beyond these are any 45nm SPARC chips, which I would expect would be Niagara3 and Rock2. Realistically, these are 2010 systems offerings. Then beyond any Niagara3 and Rock2 would be 32nm processors, (Niagara4 and Rock3?), in 2012 or later.
Sun has plenty of time, and plenty of options. First of all, TI did not say it was exiting the 32nm chip market, only the 32nm fab business. So any fab partners would have to be using process compatible with TI's semicondutor design. These TI partner fabs may be able to fab 32nm Sun SPARC chips.
Second, Fujitsu is a major semiconductor fab, and to my knowledge, has not announced much around 45nm. Perhaps Fujitsu could skip 45nm and pursue 32nm.
Intel is certainly an option, as is AMD, and even IBM. I think Freescale has some fabs as well.
And as for your comment about 32nm vs. 45nm, one process revision does not a fight make. Intel always brings out its next process on desktop systems, while its more powerful Xeon server processors lag one generation. Similarly, Intel's more powerful Itanium lags Xeon by one generation (Itanium is still 90nm, and will not go to 65nm until Tukwila in 2008). Also, AMD's very capable Opteron is still 90nm, and competed with 65nm Xeon very well. Opteron is going to 65nm and true quad-core with Barcelona, only about six months ahead of Intel's 45nm Xeon transition.
One last thing, the very powerful IBM POWER5+, Intel Montecito dual-core Itanium, and Sun UltraSPARC T1 processors are all 90nm designs, and crush any 65nm processors out there.
High-end server processors are different than desktop PC or laptop processors, and always will fall a generation or two behind the state of the art.